Chapter 3 – Atoms and Molecules - Short Notes



1. Laws of Chemical Combination


1.1 Law of Conservation of Mass

Key Definition

Law of Conservation of Mass states that mass can neither be created nor destroyed in a chemical reaction.


Explanation (Point-wise)

  • During a chemical reaction, substances only rearrange.
  • Total mass of reactants = total mass of products.
  • No new matter is created, and no matter is lost.

Example

Reaction between barium chloride and sodium sulphate:

BaCl₂ + Na₂SO₄ → BaSO₄ + 2NaCl

  • Total mass before reaction = Total mass after reaction

Diagram Description

A closed flask showing reactants before reaction and products after reaction, with equal total mass indicated on both sides.


Important Points / Exam Tips

  • Reaction must take place in a closed system.
  • Frequently asked as definition or reasoning question.
  • Supports balancing of chemical equations.

1.2 Law of Constant Proportions

Key Definition

Law of Constant Proportions states that a chemical compound always contains the same elements combined in the same proportion by mass.


Explanation (Point-wise)

  • The ratio of elements in a compound is fixed.
  • This ratio does not change regardless of source or method of preparation.

Example

Water (H₂O):

  • Hydrogen : Oxygen = 1 : 8 by mass

Diagram Description

Molecular model of water showing two hydrogen atoms and one oxygen atom.


Important Points / Exam Tips

  • Applies only to pure compounds.
  • Very important 1–2 mark theory question.
  • Helps in understanding chemical formulae.

2. Dalton’s Atomic Theory


Key Definition

Dalton’s Atomic Theory explains the nature of matter based on the concept of atoms.


Main Postulates (Point-wise)

  1. Matter is made up of tiny particles called atoms.
  2. Atoms are indivisible and cannot be created or destroyed.
  3. Atoms of the same element are identical in mass and properties.
  4. Atoms of different elements have different masses and properties.
  5. Compounds form when atoms combine in simple whole-number ratios.
  6. Chemical reactions involve rearrangement of atoms.

Diagram Description

Spherical atoms combining to form molecules in fixed ratios.


Important Points / Exam Tips

  • Explains laws of chemical combination.
  • Some postulates are modified later, but NCERT explanation is sufficient.
  • Asked as list or explanation question.

3. What is an Atom?


Key Definition

An atom is the smallest particle of an element that takes part in a chemical reaction.


Explanation (Point-wise)

  • Atoms are extremely small.
  • Cannot be seen with naked eye.
  • Represented using symbols.

Example

  • Hydrogen → H
  • Oxygen → O
  • Carbon → C

Important Points / Exam Tips

  • Atoms generally do not exist independently.
  • Noble gases are an exception.

4. What is a Molecule?


Key Definition

A molecule is the smallest particle of a substance that can exist independently and shows all properties of that substance.


Types of Molecules

Type Explanation Example
Molecules of Elements Made of same atoms O₂, N₂
Molecules of Compounds Made of different atoms H₂O, CO₂

Diagram Description

Diatomic molecule showing two atoms joined by a bond.


Important Points / Exam Tips

  • Molecules can exist independently.
  • Both elements and compounds form molecules.

5. What is an Ion?


Key Definition

An ion is a charged particle formed by loss or gain of electrons.


Types of Ions

Ion Type Charge Example
Cation Positive Na⁺, Ca²⁺
Anion Negative Cl⁻, O²⁻

Explanation (Point-wise)

  • Loss of electrons → Cation
  • Gain of electrons → Anion

Important Points / Exam Tips

  • Ions carry electrical charge.
  • Important for writing chemical formulae.

6. Writing Chemical Formulae


Key Concept

Chemical formula represents the composition of a compound.


Steps (Point-wise)

  1. Write symbols of elements.
  2. Write valencies.
  3. Criss-cross valencies.
  4. Simplify if possible.

Example

Calcium Chloride:

  • Ca²⁺ and Cl⁻
  • Formula → CaCl₂

Diagram / Flowchart Description

Flowchart showing steps from symbols → valency → criss-cross → formula.


Important Points / Exam Tips

  • Valency must be memorized.
  • No charge is written in final formula.
  • Very important for numericals.

7. Relative Atomic Mass


Key Definition

Relative atomic mass is the average mass of an atom compared to 1/12th mass of carbon-12 atom.


Explanation (Point-wise)

  • Carbon-12 is the standard.
  • Atomic mass has no unit.

Example

  • Hydrogen = 1 u
  • Oxygen = 16 u

Important Points / Exam Tips

  • Written as Ar.
  • Used in mole concept.

8. Mole Concept


Key Definition

A mole is the amount of substance that contains 6.022 × 10²³ particles.


Explanation (Point-wise)

  • 1 mole = 6.022 × 10²³ atoms/molecules/ions
  • This number is called Avogadro’s number.

Examples

  • 1 mole of oxygen atoms = 6.022 × 10²³ atoms
  • 1 mole of water molecules = 6.022 × 10²³ molecules

Important Points / Exam Tips

  • Fundamental concept for numericals.
  • Always write Avogadro’s number correctly.

9. Molar Mass


Key Definition

Molar mass is the mass of one mole of a substance.


Explanation

  • Unit: g/mol
  • Numerically equal to atomic or molecular mass.

Example

  • Molar mass of H₂O = 2(1) + 16 = 18 g/mol

Important Points / Exam Tips

  • Used in mass–mole conversions.
  • Frequently asked in numericals.

10. Numericals Based on Mole Concept


Formulae to Remember

  • Number of moles = Mass / Molar mass
  • Number of particles = Moles × Avogadro’s number

Important Points / Exam Tips

  • Units must be written properly.
  • Step-wise calculation fetches full marks.
  • Common in 3–5 mark questions.

Quick Revision Summary – Atoms and Molecules

  • Matter follows laws of chemical combination.
  • Atoms are basic building blocks of matter.
  • Molecules and ions are formed from atoms.
  • Chemical formulae depend on valency.
  • Mole concept links mass, moles, and number of particles.
  • Avogadro’s number = 6.022 × 10²³.
  • Molar mass is essential for solving numericals.


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