Chapter 1 – Chemical reactions and equations - Short Notes

Every day, many changes occur around us. Some are physical changes, while others are chemical changes. Whenever a substance changes into a completely new substance with different properties, a chemical reaction takes place.

Daily Life Examples of Chemical Reactions

  • Milk turning sour
  • Rusting of iron
  • Fermentation of grapes
  • Cooking food
  • Digestion
  • Respiration

In all these cases, new substances are formed.


HOW DO WE KNOW A CHEMICAL REACTION HAS OCCURRED?

A chemical reaction can be identified by observing:

  1. Change in state
  2. Change in colour
  3. Evolution of gas
  4. Change in temperature

ACTIVITY: BURNING OF MAGNESIUM RIBBON

When magnesium ribbon is burnt in air:

  • It burns with a dazzling white flame.
  • White ash of magnesium oxide is formed.

Reaction

Observation

  • Bright white flame
  • White powder formed

Important Point

Magnesium ribbon is cleaned before burning because it has a layer of magnesium oxide on its surface which prevents proper burning.


CHEMICAL EQUATIONS

A chemical equation represents a chemical reaction using symbols and formulae.

Word Equation

Magnesium + Oxygen → Magnesium oxide

Chemical Equation

Reactants

Substances taking part in reaction.

Products

New substances formed.


BALANCED CHEMICAL EQUATION

According to the Law of Conservation of Mass, atoms can neither be created nor destroyed during a chemical reaction.

Therefore:

  • Number of atoms on LHS = Number of atoms on RHS

Such an equation is called a balanced chemical equation.


STEPS FOR BALANCING CHEMICAL EQUATIONS

Example:

Balanced Equation:

Hit and Trial Method

  • Balance one element at a time.
  • Never change chemical formula.
  • Only add coefficients.

PHYSICAL STATES IN CHEMICAL EQUATIONS

Symbols used:

  • (s) → solid
  • (l) → liquid
  • (g) → gas
  • (aq) → aqueous solution

Example:


TYPES OF CHEMICAL REACTIONS


1. COMBINATION REACTION

A reaction in which two or more substances combine to form a single product.

Example 1: Formation of Slaked Lime

Quick lime reacts with water producing slaked lime and heat.

Observation

  • Beaker becomes hot.
  • Heat is released.

This is also an exothermic reaction.


Whitewashing Reaction

Slaked lime reacts with carbon dioxide forming calcium carbonate.

Important Point

  • Calcium carbonate gives shiny finish to walls.
  • Marble is also chemically calcium carbonate.

Other Examples of Combination Reactions

Burning of Coal

Formation of Water


EXOTHERMIC REACTIONS

Reactions that release heat energy.

Example: Burning of Methane


Respiration – An Exothermic Reaction

Glucose reacts with oxygen to release energy.

Important Point

  • Energy released keeps living organisms alive.

2. DECOMPOSITION REACTION

A reaction in which a single compound breaks into simpler substances.


Activity: Heating Ferrous Sulphate

Green ferrous sulphate crystals lose water and decompose.

Observations

  • Green colour changes.
  • Smell of burning sulphur comes.

Reaction:


Thermal Decomposition of Limestone

Important Points

  • Calcium oxide = Quick lime
  • Used in cement manufacture

Heating Lead Nitrate

Brown fumes of nitrogen dioxide are produced.

Observation

  • Brown fumes observed

ELECTROLYTIC DECOMPOSITION OF WATER

Electricity decomposes water into hydrogen and oxygen.

Important Point

Hydrogen collected is double the volume of oxygen because water contains hydrogen and oxygen in 2:1 ratio.


PHOTOCHEMICAL DECOMPOSITION

Silver Chloride in Sunlight

White silver chloride turns grey.

Silver Bromide Reaction

Applications

  • Used in black and white photography.

ENDOTHERMIC REACTIONS

Reactions that absorb energy.

Examples:

  • Decomposition reactions
  • Electrolysis
  • Photosensitive reactions

3. DISPLACEMENT REACTION

A more reactive element displaces a less reactive element from its compound.

Iron and Copper Sulphate Reaction

Observations

  • Blue colour fades.
  • Iron nail becomes brown.

Reaction:

Explanation

Iron is more reactive than copper.


Other Examples

Zinc Displacing Copper

Lead Displacing Copper


4. DOUBLE DISPLACEMENT REACTION

Two compounds exchange ions to form new compounds.

Sodium Sulphate and Barium Chloride

White precipitate of barium sulphate is formed.

Important Point

  • White insoluble solid = precipitate
  • Hence called precipitation reaction.

LEAD NITRATE + POTASSIUM IODIDE REACTION

Yellow precipitate of lead iodide forms.

Observation

  • Bright yellow precipitate formed.

5. OXIDATION AND REDUCTION (REDOX REACTIONS)


OXIDATION

Addition of oxygen OR removal of hydrogen.

Example

Copper forms black copper oxide on heating.

Copper gains oxygen → Oxidation


REDUCTION

Removal of oxygen OR addition of hydrogen.

Example

Explanation

  • CuO loses oxygen → Reduced
  • H₂ gains oxygen → Oxidised

OTHER REDOX REACTIONS

Zinc Oxide Reduction

Manganese Dioxide Reaction


EFFECTS OF OXIDATION IN DAILY LIFE


CORROSION

When metals react with moisture, air or acids and get damaged.

Examples

  • Rusting of iron
  • Green coating on copper
  • Black coating on silver

Rusting

Iron reacts with oxygen and moisture forming reddish brown rust.

Prevention

  • Painting
  • Greasing
  • Galvanisation

RANCIDITY

Oxidation of oils and fats causing bad smell and taste.

Prevention

  • Use airtight containers
  • Add antioxidants
  • Refrigeration
  • Flushing nitrogen gas in chips packets

Important Example

Nitrogen gas is filled in chips packets to prevent oxidation.

 


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